Why Do Ice Cubes From the Freezer Crack and Pop in a Drink?
― Ice Can Tear Itself Apart With a Difference of Just a Few Degrees
Drop an ice cube fresh from the freezer into barley tea, and it goes crack, snap, and white fractures race through it. Nobody hit it. So why does the ice break? The answer has two parts: "only the outside warms up and swells suddenly", and "ice is very bad at being pulled". The numbers show that ice can break with a temperature difference of only about 2°C. It is a surprisingly delicate material.
It is a hot afternoon. You put ice in a glass and pour in cold barley tea. At that moment, small pinging sounds come from the glass.
Look closer, and the ice that was clear a moment ago now has white, plate-like cracks inside it. Some cubes even split clean in two.
But if you use ice that has sat on the counter for a while, there is hardly any sound. It is the same ice. So what is different?
There are only two reasons ice breaks
Water passes heat on very quickly. The moment ice goes into a drink, only its surface warms to 0°C and tries to expand. But the core is still cold and stays shrunken.
The swelling outside pulls the core outward in every direction. Ice is strong when squeezed but very weak when stretched. The core cannot take it and splits from the inside.
So the ice is not being broken from outside. Its own outside and inside, at different temperatures, pull against each other until it cracks. Let's take it one step at a time.
Reason 1: Only the surface swells, while the core stays shrunken
A home freezer is usually kept at around −18°C. Ice just out of it is cold to the core, all the way through.
When you put this ice in a drink, heat floods in from the liquid around it. Water is much better at passing on heat than air is. So the surface of the ice quickly warms to nearly 0°C. Heat takes time to travel through the ice, though, so the core stays at −18°C for a while.
Most things swell slightly when they warm up, and ice is no different. The surface layer "wants to grow a little bigger", but the cold core stays small. Outside and inside are joined as one piece, so the mismatch has nowhere to go. In Figure 1 you can see the outside pulling the core outward.
Ice left out in the air is less likely to crack because air passes on heat only slowly. While the surface warms bit by bit, heat reaches the core too, so the gap between outside and inside never opens wide.
Reason 2: Ice is very weak when pulled
Ice is hard. Even the blade of a shaved-ice machine does not make it crumble at once. It has a fair amount of strength against being crushed.
But it is very weak against pulling. The force that breaks ice by pulling is said to be only a fraction of the force that breaks it by crushing, from a few times smaller to about a tenth. Ice also cannot stretch like rubber to spread out the force. Once it goes even slightly past its limit, a crack runs through it at once.
The outer layer that swelled in Reason 1 pulls the core outward in every direction. So the core gets the kind of force ice likes least: a pull. That is why the cracks form inside rather than on the surface. The "crack" sound is the ice vibrating as the fracture spreads in an instant.
So how big a temperature difference does it take? In Figure 2, change the freezer temperature and find out.
The bar in Figure 2 is an upper-limit estimate: the outside is exactly 0°C and the core stays at freezer temperature. In reality, the temperature changes gradually, so the force is smaller than this. Even so, for −18°C ice it exceeds the breaking strength many times over. You can see that ice is a material that "breaks as a matter of course".
Very thin gaps of air form inside the cracks. Light reflects off the boundary between ice and air, so white, glinting plates appear inside the clear ice. Snow looks white for the same reason.
If you take ice out of the freezer and leave it for a minute or two before using it, it cracks less. Wait until a little water seeps onto the surface, and the temperature difference with the core gets smaller. In the world of cocktails and spirits, this extra step is sometimes called "tempering the ice". It also helps when you want to use clear ice without breaking it.
Summary
Ice put into a drink has only its surface warm suddenly to 0°C and swell. The cold core stays shrunken, so the outside pulls it in every direction. Ice is very weak when pulled, and the calculation says it can break with a difference of only about 2°C. That is why −18°C ice splits from the inside with a crack and a pop.
It is not the drink that breaks the ice.
It is the tug-of-war between the warmed outside and the still-cold core.
Stones breaking from temperature differences in the same way are covered in "Why do river stones sometimes crack and fly apart when you build a fireplace with them?", and water passing heat faster than air is covered in "A sauna is 90°C, so why can we stand it?". For why cracks look white, "Ice is clear, so why does snow look white?" is a useful read.
- Take two ice cubes out of the freezer. Put one straight into a glass of water. Hold your ear close and watch for the sound and the cracks.
- Leave the other on a plate for about 2 minutes. When the surface turns wet, put it into water in another glass. Compare the sound and cracks in the same way.
- If you have time, try lukewarm water instead of water. See whether a bigger temperature difference gives more cracks.
Pieces of broken ice can have sharp edges. Do not grip them hard in your bare hand, and take care not to cut your mouth on the rim of the glass. Do not use boiling water.
For those who want to know more ― terms, formulas and links to textbooksShows which level each part sits at, from middle-school science to university courses
- Middle schoolCovered in middle-school science
- High schoolCovered in high-school "Physics"
- High school+Advanced high-school material, or treated as a textbook sidebar
- UniversityUniversity-level specialist subjects (mechanics of materials, fracture mechanics), not taught in high school
- ResearchTopics not yet settled even at university level, which researchers are studying right now
Middle schoolTerms: this phenomenon has names
- Thermal expansion: when something warms up, its volume grows slightly. Ice swells when it warms too.
- Thermal stress: the pushing and pulling forces that arise inside an object because the temperature differs from place to place.
- Thermal shock: when something breaks from thermal stress after being heated or cooled suddenly. A glass cracking when you pour boiling water into it is the same thing.
Middle schoolHigh schoolChecking with a formula: how much pull acts on the core of freezer ice
Suppose the outer layer is at 0°C and the core stays at freezer temperature. We estimate the force that arises when the fraction by which the outside tries to lengthen is pushed straight back.
| In symbols | σ = E × α × ΔT |
| In words | Inner force = stiffness of ice × stretch per 1°C × temperature difference |
| Where it comes from | Put the fraction of stretch from a temperature difference (α × ΔT) into Hooke's law (force = stiffness × fraction of stretch). It is the upper limit, for when the swelling is completely held back |
| σ | Thermal stress. The force acting inside the ice (unit: MPa = 1 million newtons per square metre) |
| E | Young's modulus. A quantity for the stiffness of ice (how hard it is to stretch) (unit: MPa) |
| α | Coefficient of linear expansion. How much the length grows per 1°C of warming (unit: 1/℃) |
| ΔT | Temperature difference between the outside and the core (unit: ℃) |
| Young's modulus of ice, E | said to be about 9000 MPa |
| Coefficient of linear expansion of ice near 0°C, α | said to be about 0.00005 /℃ |
| Temperature difference ΔT between freezer ice and the surface at 0°C | 18 ℃ |
| Strength at which ice breaks when pulled | said to be about 0.7–3 MPa (here we use a smaller value, 1 MPa) |
| Force from a 1℃ difference | 9000 × 0.00005 = 0.45 MPa |
| Force from a difference of 18℃ | 0.45 × 18 = 8.1 MPa |
| How many times the breaking strength | 8.1 ÷ 1 = 8.1 times |
| Temperature difference where breaking starts | 1 ÷ 0.45 ≒ 2.2 ℃ |
By this estimate, a temperature difference of only about 2°C reaches the strength at which ice breaks. 8.1 MPa is about the same as pulling with roughly 80 kg per square centimetre. In reality the temperature changes smoothly, so the force is smaller than this, but this difference in order of magnitude is enough to explain why −18°C ice breaks so easily.
High schoolHigh school+Why does it break so easily only "when it goes into water"?
High schoolHeat flows from the hotter side to the colder side. Liquid water passes far more heat to the surface of an object than air does, even at the same temperature difference. So in a drink, only the surface of the ice warms suddenly, and the gap between outside and core opens wide.
High school+The depth to which heat soaks into ice grows in proportion to the square root of time (thermal diffusion). In the first few seconds after the ice goes in, the warmed layer is very thin, and a steep temperature slope forms just inside it. The steeper the slope, the greater the thermal stress. In air, which warms things slowly, the slope is gentle and the ice breaks less easily.
UniversityBrittle fracture, and resistance to thermal shock
In mechanics of materials, a failure like that of ice, which breaks all at once without stretching, is called "brittle fracture". According to fracture mechanics, objects already contain tiny flaws and bubbles, and a pulling force concentrates at their tips. This is why ice is far weaker when pulled than when crushed. Resistance to thermal shock can be compared using the breaking strength divided by E × α. Ice has a small value here and is said to be a material that withstands thermal shock worse than glass.
📖 Derivations of the formula and further reading: Thermal stress (Wikipedia, in Japanese) / Fracture mechanics (Wikipedia, in Japanese)
ResearchWhat is still not clear
- Where does the very first crack start? Bubbles and crystal boundaries inside the ice are thought to be the starting points, but predicting in advance which flaw a crack will run from is still a hard problem.
- Crystal size and how easily ice breaks. Ice with larger crystal grains has been reported to be weaker when pulled. How grain direction and impurities matter is still being studied.
- Links to how sea ice and glaciers break. Lake and sea ice that splits with a loud noise on a bitterly cold night is also said to involve thermal stress. How cracks spread at scales from a few metres to several kilometres is being investigated now.
So the content of this article too is "an explanation within what is known today". The numbers used here are rough guides that change with how the ice was made and its temperature.
Links to textbooks (by level)
| Level | Subject / unit | Where in this article |
|---|---|---|
| Middle school | Science: "Changes of state", "How heat travels" | Things swelling when warmed, water passing heat quickly |
| High school | Physics: "Heat and temperature", "Elastic force (Hooke's law)" | Checking with a formula (σ = E × α × ΔT) |
| High school+ | Advanced physics: "Heat conduction" | The warmed layer being thin and the temperature slope steep |
| University | Mechanics of materials, fracture mechanics | Brittle fracture, how to compare resistance to thermal shock |
| Research | Physical properties of ice, snow and ice science | Where cracks start, the link to crystal size |
| ― | Links to daily life | Letting ice temper for a minute or two before use; not putting cold things on hot glass |
- Petrovic, J. J. (2003) Review: Mechanical properties of ice and snow. Journal of Materials Science 38, 1–6
- Schulson, E. M. & Duval, P. (2009) Creep and Fracture of Ice. Cambridge University Press
- Hobbs, P. V. (1974) Ice Physics. Oxford University Press
- National Astronomical Observatory of Japan (国立天文台), ed., Rika Nenpyo (理科年表, Chronological Scientific Tables), Maruzen Publishing (physics/chemistry section: physical properties of ice)
*This article is a popular-science explanation for general readers. The figures given are rough guides to help you understand how things work. The physical properties of ice vary greatly with how it was made, its temperature and how many bubbles it contains.